DPF:アッシュ②

今回はDPF最大の難敵、ラスボス「アッシュ」について書きたいと思います。
(上の写真は洗浄時に落とした汚れからアッシュを分離・乾燥させたものです)


アッシュの主成分とし て硫酸カルシウムや硝酸カルシウムなどが挙げられます。
硫酸カルシウムと一言で言ってもピンと来ないと思いますが、
要するに石膏です。
(詳しいことはネット検索すると多数論文が出てきますのでそちらで勉強して下さい)

DPFフィルターの中で石膏がフィルターの内壁を塞ぎ「フィルター詰まり」を起こします。
ではなぜアッシュが生成されるかと言うと・・・エンジンオイルです。
エンジンオイル内に含まれる洗浄成分等(不燃燃焼生成物)が原因とされています。

さて最近は「アッシュを燃焼」だの、「アッシュを分解」だの、「アッシュを粉砕」だの、
様々な謳い文句で洗浄を押している業者さんを多数見かけます。

あえて物申します。
アッシュは分解できません(正確には出来ますが、DPFフィルターも一緒に溶けてなくなります)
アッシュは燃焼も出来ません(正確には出来ますが、DPFフィルターも一緒に燃焼します)

分解について・・・DPFフィルターから剥がした状態でなら分解も可能かもしれませんが、
まずセラミックの方が耐えられません(酸を使っても容易に分解できない「難溶性物質」です)。

燃焼について・・・アッシュはDPF内で二水石膏→半水石膏→DPF内で焼成→高温型無水石膏になります。
その燃焼温度は1000℃超です。
DPFフィルター(セラミック)は800℃~1000℃位までしか耐えられません。

粉砕について・・・確実にセラミックフィルターの表面もしくは内壁が一緒に剥がれます。
そもそもアッシュ成分のみ粉砕することなど不可能です。


機械式洗浄で圧力をかけて洗う事もこの粉砕と同じ事です。
結果的にDPFフィルターの内壁が剥がれて薄くなっている為洗浄後の差圧は下がりますが、
DPFフィルターの寿命を大きく縮める行為としか言いようが有りません。
(高圧洗浄で洗うのは論外です。あれはただの破壊行為です。)
(セラミックフィルターの小さなセルの中に高圧が掛かったらどうなるか、子供でも分かりそうなものですが・・・)

ではどうするのか?

何度も行ってきましたが、手洗いで丁寧に流して行くしかないのです。
高温型無水石膏もホントに少しづつですが「水和」します。
これを利用してアッシュ(硫酸カルシウム)を少しづつ浮かせて、丁寧に剥ぎ取るしかないのです。
その手間をかけて初めて「DPFフィルターの寿命と洗浄のバランス」が取れるのです。

何度も言っておきます。


ディーゼル自動車用DPFのアッシュを分解・燃焼・粉砕等は
全て今現在の技術では不可能です。


騙されないように注意しましょう!

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